Phase separation
#1
Phase separation
I wanted to talk about phase separation, My wifes car today decided to run rough and wanted to stall. No codes were thrown and ran better later. This time of year with the colder mornings and ethanol gas sold everywhere now there is going to be a lot of problems that people are not used to. Here are a few tips that I use.
1. Keep fuel tank full. Moisture from the air will condensed on the side of tank and fall into the gas. Water will separate at 50-60 degrees depending on water content.
2. People use Heet in the yellow bottle especially down south, Not needed ethanol in the gas does the same thing. If you still want to use Heet use the red bottle Iso-heet its better for the gas and motor. Heet in the yellow bottle is Methanol and is very corrosive to aluminium motors and sensors, was made for iron blocks along time ago. Iso-heet is safe. Ethanol is corrosive too but no where near as bad as methanol.
My son took my wifes car and put a few gallons of premium gas in and the problem is fixed. When gas separates the gas left over is lower octane so adding a few gallons of premium raises the octane back to 87 or higher. I did not have this problem this morning because I use premium. Premium gas holds in suspension more water so if phase separation happens the octane level will still be higher that 87.
I am not pushing premium but a few gallons every once in a while will help. I plan on using regular over the winter because of the cold, higher octane is not needed.
If any one has other ideas post them here.
1. Keep fuel tank full. Moisture from the air will condensed on the side of tank and fall into the gas. Water will separate at 50-60 degrees depending on water content.
2. People use Heet in the yellow bottle especially down south, Not needed ethanol in the gas does the same thing. If you still want to use Heet use the red bottle Iso-heet its better for the gas and motor. Heet in the yellow bottle is Methanol and is very corrosive to aluminium motors and sensors, was made for iron blocks along time ago. Iso-heet is safe. Ethanol is corrosive too but no where near as bad as methanol.
My son took my wifes car and put a few gallons of premium gas in and the problem is fixed. When gas separates the gas left over is lower octane so adding a few gallons of premium raises the octane back to 87 or higher. I did not have this problem this morning because I use premium. Premium gas holds in suspension more water so if phase separation happens the octane level will still be higher that 87.
I am not pushing premium but a few gallons every once in a while will help. I plan on using regular over the winter because of the cold, higher octane is not needed.
If any one has other ideas post them here.
#2
Where did you read that premium holds more water in solution? Intuitively I think it would be the same as regular.
An interesting footnote is that gasoline with ethanol is less likely to experience phase separation because it does hold more water in solution.
link.
I'm not going to worry about water in my gas. Never have. Just don't buy from seedy side street sellers of questionable fuel. Never ran premium either except in a car that recommends or requires it.
An interesting footnote is that gasoline with ethanol is less likely to experience phase separation because it does hold more water in solution.
Conclusion
Water phase separation in any gasoline is most likely to
occur when liquid water comes in contact with the fuel. (Water
in the form of moisture in the air will generally not cause phase
separation.) Water which is in solution with gasoline is not a
problem in any engine, but as a separate phase it can prevent an
engine from running or even cause damage. Since oxygenated
gasolines [i.e. gasoline with ethanol], however, can hold more water than conventional
gasoline, phase separation is less likely to occur with
oxygenates present.
Water phase separation in any gasoline is most likely to
occur when liquid water comes in contact with the fuel. (Water
in the form of moisture in the air will generally not cause phase
separation.) Water which is in solution with gasoline is not a
problem in any engine, but as a separate phase it can prevent an
engine from running or even cause damage. Since oxygenated
gasolines [i.e. gasoline with ethanol], however, can hold more water than conventional
gasoline, phase separation is less likely to occur with
oxygenates present.
I'm not going to worry about water in my gas. Never have. Just don't buy from seedy side street sellers of questionable fuel. Never ran premium either except in a car that recommends or requires it.
#5
I take it you don't have anything to support yet another Silver Bullet endorsement for the use of premium fuel in an economy car.
#6
My wife uses your regular in her car and has 4000 miles and is happy getting 25 mpg on it, so if premium prevents the effects of phase separation and the trip to a dealer so be it. Keep in mind I get 40 plus in the same kind of car. I drove city today to pick up my son and still got 40 plus, I actually drove the car hard and got better mileage then highway using premium.
Last edited by SilverBullet; 09-04-2010 at 11:07 PM.
#7
reference, please? (I googled but my searches failed to find any).
It's ironic that you're unable to convince your wife of the benefits of premium gas. I finally got mine to stop putting premium in her 98 Camry, but she still insists on changing the oil every 3,000 miles (the dealer said to!).
It's ironic that you're unable to convince your wife of the benefits of premium gas. I finally got mine to stop putting premium in her 98 Camry, but she still insists on changing the oil every 3,000 miles (the dealer said to!).
#8
Here is info on phase separation
Fuel School: Phase Separation in Ethanol Blended Gasoline
What is ?phase separation??
Phase Separation in Gasoline
Keep in mind that winter blends dont come out until Oct 15, so summer gas can separate in cooler temp than normal.
Fuel School: Phase Separation in Ethanol Blended Gasoline
What is ?phase separation??
Phase Separation in Gasoline
Keep in mind that winter blends dont come out until Oct 15, so summer gas can separate in cooler temp than normal.
#9
Here is info on phase separation
Fuel School: Phase Separation in Ethanol Blended Gasoline
What is ?phase separation??
Phase Separation in Gasoline
Keep in mind that winter blends dont come out until Oct 15, so summer gas can separate in cooler temp than normal.
Fuel School: Phase Separation in Ethanol Blended Gasoline
What is ?phase separation??
Phase Separation in Gasoline
Keep in mind that winter blends dont come out until Oct 15, so summer gas can separate in cooler temp than normal.
edit: or preventing the "effects" of phase separation. Once your gas has separated you've got a problem that requires emptying the tank. Adding more fuel, premium or otherwise, just postpones the problem; it's unlikely the water and/or ethanol will go back into solution with the gasoline leaving a layer of potentially damaging liquid at the bottom of your tank.
If you're saying ethanol contributes to the likelihood of phase separation, the link I provided, as well as your own opening post (mentions HEET) state the opposite.
Last edited by Steve244; 09-04-2010 at 11:30 PM.
#10
She knows when I run premium in her cars, I told her not too. I wanted to compare the two cars until this problem came up. I go once a year on oil change in her van sometimes longer. So what are you going to do when your Camry starts acting up,blame it on premium? All I am saying is there is a purpose for premium and many cars will run fine on regular, but if you add up all the extra maintenance and other related cost is it worth it to run regular.
#11
What extra maintenance and related costs using regular? You have yet to show any...
#12
uh thanks, but that says nothing about premium fuel preventing phase separation.
edit: or preventing the "effects" of phase separation. Once your gas has separated you've got a problem that requires emptying the tank. Adding more fuel, premium or otherwise, just postpones the problem; it's unlikely the water and/or ethanol will go back into solution with the gasoline leaving a layer of potentially damaging liquid at the bottom of your tank.
If you're saying ethanol contributes to the likelihood of phase separation, the link I provided, as well as your own opening post (mentions HEET) state the opposite.
edit: or preventing the "effects" of phase separation. Once your gas has separated you've got a problem that requires emptying the tank. Adding more fuel, premium or otherwise, just postpones the problem; it's unlikely the water and/or ethanol will go back into solution with the gasoline leaving a layer of potentially damaging liquid at the bottom of your tank.
If you're saying ethanol contributes to the likelihood of phase separation, the link I provided, as well as your own opening post (mentions HEET) state the opposite.
Here is a link that explain the lowering of octane in phase separation
Gasoline Octane and E10 Ethanol Blend Fuels
As far as heet, Ive used in the past in my older cars before I started to use premium. If heet is so good thats why they change formula to Iso heet.
Here is a short write up on isopropyl alcohol Iso heet
Methanol-gasoline blends: blending agents to prevent phase separation
David W. Ostena and Nancy J. Sell*
aUniversity of Washington, Seattle USA
*University of Wisconsin-Green Bay, Green Bay, WI 54302, USA
Received 29 December 1981; revised 10 August 1982. Available online 12 August 2003.
Abstract
The use of methanol-gasoline blends as automotive fuel is limited, in part, by phase separation at low temperatures. The separation temperature of these mixtures can be adjusted by varying the percentage of blending agent present. Two blending agents were considered in this study, tertiary butyl alcohol and isopropyl alcohol. Both were found to significantly lower the separation temperature, although, isopropyl alcohol is more effective, possibly due to its greater ability to form hydrogen bonds. Correlation equations were derived relating the percentage compositions and the separation temperature.
#13
Nope, she switched to regular in 2008 when gas prices were so high. Not noticing any difference finally convinced her that premium was a waste of money. I'd like to think it was my use of logic and facts, but well, you know how that goes.
What gas station to you go to? Shell I was told is higher than 87 octane from a few rep-able sources.
What extra maintenance and related costs using regular? You have yet to show any...
What gas station to you go to? Shell I was told is higher than 87 octane from a few rep-able sources.
What extra maintenance and related costs using regular? You have yet to show any...
#14
There was only a few gallons of gas and premium hold more water in suspension.
Here is a link that explain the lowering of octane in phase separation
Gasoline Octane and E10 Ethanol Blend Fuels
As far as heet, Ive used in the past in my older cars before I started to use premium. If heet is so good thats why they change formula to Iso heet.
Here is a short write up on isopropyl alcohol Iso heet
Methanol-gasoline blends: blending agents to prevent phase separation
David W. Ostena and Nancy J. Sell*
aUniversity of Washington, Seattle USA
*University of Wisconsin-Green Bay, Green Bay, WI 54302, USA
Received 29 December 1981; revised 10 August 1982. Available online 12 August 2003.
Abstract
The use of methanol-gasoline blends as automotive fuel is limited, in part, by phase separation at low temperatures. The separation temperature of these mixtures can be adjusted by varying the percentage of blending agent present. Two blending agents were considered in this study, tertiary butyl alcohol and isopropyl alcohol. Both were found to significantly lower the separation temperature, although, isopropyl alcohol is more effective, possibly due to its greater ability to form hydrogen bonds. Correlation equations were derived relating the percentage compositions and the separation temperature.
Here is a link that explain the lowering of octane in phase separation
Gasoline Octane and E10 Ethanol Blend Fuels
As far as heet, Ive used in the past in my older cars before I started to use premium. If heet is so good thats why they change formula to Iso heet.
Here is a short write up on isopropyl alcohol Iso heet
Methanol-gasoline blends: blending agents to prevent phase separation
David W. Ostena and Nancy J. Sell*
aUniversity of Washington, Seattle USA
*University of Wisconsin-Green Bay, Green Bay, WI 54302, USA
Received 29 December 1981; revised 10 August 1982. Available online 12 August 2003.
Abstract
The use of methanol-gasoline blends as automotive fuel is limited, in part, by phase separation at low temperatures. The separation temperature of these mixtures can be adjusted by varying the percentage of blending agent present. Two blending agents were considered in this study, tertiary butyl alcohol and isopropyl alcohol. Both were found to significantly lower the separation temperature, although, isopropyl alcohol is more effective, possibly due to its greater ability to form hydrogen bonds. Correlation equations were derived relating the percentage compositions and the separation temperature.
#15
Added detergents (if they are really more than regular fuels) are not what make premium fuel "premium." The premium aspect is additives to raise the octane rating. In the case of your site above this is ethanol, which lowers energy content and will have a negative effect on fuel efficiency.
I advocate buying fuel from a station that is less likely to have phase separation (i.e. water in their storage tanks). The amount of traffic the station receives and its general maintenance (i.e. well maintained pumps, hoses, nozzles, grounds and general age) is an indicator. Price and grade at the station have little to do with it. Premium fuel, by virtue of its price may actually have sat in the station's storage tanks longer making it more likely to have problems!
If you think you have phase separation, water or ethanol, in your tank, the best thing to do is take it to a mechanic and have the tank drained and filled with fresh clean gasoline.
#16
If your argument, as this site suggests, is that premium fuel is premium because they add more ethanol than regular to raise the octane rating thus making its ability to hold water in solution greater, it sorta lays waste to all your other premium fuel claims about added power and efficiency. You have argued profusely on this point, Mr. Bullet. You can't have it both ways.
Premium gas has etbe,butanols and other alcohols which have a lower oxygen content so more is needed. Cheap gas has more ethanol and most premiums are considered ethanol free Ethanol Free Premium Coalition
#17
Premium gasoline may have more detergents than regular. Can you provide any reference that supports this claim? Something besides the manufacturers' claims would be helpful.
Added detergents (if they are really more than regular fuels) are not what make premium fuel "premium." The premium aspect is additives to raise the octane rating. In the case of your site above this is ethanol, which lowers energy content and will have a negative effect on fuel efficiency.
I advocate buying fuel from a station that is less likely to have phase separation (i.e. water in their storage tanks). The amount of traffic the station receives and its general maintenance (i.e. well maintained pumps, hoses, nozzles, grounds and general age) is an indicator. Price and grade at the station have little to do with it. Premium fuel, by virtue of its price may actually have sat in the station's storage tanks longer making it more likely to have problems!
If you think you have phase separation, water or ethanol, in your tank, the best thing to do is take it to a mechanic and have the tank drained and filled with fresh clean gasoline.
Added detergents (if they are really more than regular fuels) are not what make premium fuel "premium." The premium aspect is additives to raise the octane rating. In the case of your site above this is ethanol, which lowers energy content and will have a negative effect on fuel efficiency.
I advocate buying fuel from a station that is less likely to have phase separation (i.e. water in their storage tanks). The amount of traffic the station receives and its general maintenance (i.e. well maintained pumps, hoses, nozzles, grounds and general age) is an indicator. Price and grade at the station have little to do with it. Premium fuel, by virtue of its price may actually have sat in the station's storage tanks longer making it more likely to have problems!
If you think you have phase separation, water or ethanol, in your tank, the best thing to do is take it to a mechanic and have the tank drained and filled with fresh clean gasoline.
I buy from high traffic gas stations too. Premium dont cost me more, I get better mileage and what you dont understand is if you get 24 miles more out of a tank, its the cost difference of the two fuels.
Shell V-Power® - United States
Fuels | Amoco UltimateŽ with Invigorate
http://www.bp.com/sectiongenericarti...tentId=7009025 Bp in UK. notice that they say 28 miles further. Its the same gas here.
Last edited by SilverBullet; 09-05-2010 at 02:10 PM.
#18
The law says 3.5 percent oxygen which is 10 percent ethanol. Most gas is 8 percent ethanol.
Premium gas has etbe,butanols and other alcohols which have a lower oxygen content so more is needed. Cheap gas has more ethanol and most premiums are considered ethanol free Ethanol Free Premium Coalition
Premium gas has etbe,butanols and other alcohols which have a lower oxygen content so more is needed. Cheap gas has more ethanol and most premiums are considered ethanol free Ethanol Free Premium Coalition
The link you provided is an individual's call to "petition" for ethanol free premium gasoline. It doesn't state that premium is ethanol free; quite the opposite.
If premium were ethanol free, then its ability to retain water in solution is less than regular (assuming regular has ethanol).
Premium may have more ethanol than regular (as pointed out in the link you provided above) resulting in less energy.
The octane rating of premium fuel is the only difference; the fuel's tendency to resist knock. Not energy. Not its ability to hold water in solution.
Draining the tank and changing fuel filter, Tow, and clean gas cost more than premium would in your cars life time.
I buy from high traffic gas stations too. Premium dont cost me more, I get better mileage and what you dont understand is if you get 24 miles more out of a tank, its the cost difference of the two fuels.
Shell V-Power® - United States
Fuels | Amoco UltimateŽ with Invigorate
BP Ultimate UK - Higher octane Bp in UK. notice that they say 28 miles further. Its the same gas here.
I buy from high traffic gas stations too. Premium dont cost me more, I get better mileage and what you dont understand is if you get 24 miles more out of a tank, its the cost difference of the two fuels.
Shell V-Power® - United States
Fuels | Amoco UltimateŽ with Invigorate
BP Ultimate UK - Higher octane Bp in UK. notice that they say 28 miles further. Its the same gas here.
The links for Shell and BP are nice. They may actually have more detergents in their premium fuel than they do in their regular fuel, however they don't actually state this. All they compare their premium brands with is with the federally mandated minimum standard. No where do they compare with their own brands of regular fuel in terms of detergents. If "top tier" is to be believed (another dubious marketing effort created by Quick Trip) their regular gasoline adheres to the same standard.
Gasoline retailers must meet the high TOP TIER standards with all grades of gasoline to be approved by the automakers as providing TOP TIER Detergent Gasoline.
#19
BP Ultimate UK - Higher octane Bp in UK. notice that they say 28 miles further. Its the same gas here.
Can take you 28 miles further than what? Not putting fuel in your car? This is marketing nonsense. It's a meaningless statement.
And no, it's not the same gas as here. UK requirements are not the same as US, either federal or local.
#20
Did you notice this is an advertisement by the seller?
Can take you 28 miles further than what? Not putting fuel in your car? This is marketing nonsense. It's a meaningless statement.
And no, it's not the same gas as here. UK requirements are not the same as US, either federal or local.
Can take you 28 miles further than what? Not putting fuel in your car? This is marketing nonsense. It's a meaningless statement.
And no, it's not the same gas as here. UK requirements are not the same as US, either federal or local.
I never said that the Fit cant use regular. There are benefits from premium.
Last edited by SilverBullet; 09-06-2010 at 09:31 PM.